β-Carbon nitride

β-Carbon nitride (beta-carbon nitride), β-C3N4, is a superhard material predicted to be harder than diamond.

Β-Carbon nitride

Lattice structure of (β-C3N4).]]
Names
IUPAC name
β-Carbon nitride
Identifiers
3D model (JSmol)
MeSH Carbon+nitride
  • InChI=1S/N4C3/c1-5-2-6(1)3(5)7(1,2)4(5)6
  • N13[C]25N4[C]16N2[C]34N56
Properties
C3N4
Molar mass 92.061 g·mol−1
Structure
Hexagonal, hP14
P63/m No. 176
a = 6.36 Å, c = 4.648 Å
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

The material was first proposed in 1985 by Amy Liu and Marvin L. Cohen. Examining the nature of crystalline bonds they theorised that carbon and nitrogen atoms could form a particularly short and strong bond in a stable crystal lattice in a ratio of 1:1.3, and that this material could be harder than diamond.

Nanosized crystals and nanorods of β-carbon nitride can be prepared by mechanochemical processing.

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