Benzene-1,2-dithiol

Benzene-1,2-dithiol is the organosulfur compound with the formula C6H4(SH)2. This colourless viscous liquid consists of a benzene ring with a pair of adjacent thiol groups. The conjugate base of this diprotic compound serves as chelating agent in coordination chemistry and a building block for the synthesis of other organosulfur compounds.

Benzene-1,2-dithiol
Names
Preferred IUPAC name
Benzene-1,2-dithiol
Other names
1,2-Dimercaptobenzene
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.037.740
UNII
  • InChI=1S/C6H6S2/c7-5-3-1-2-4-6(5)8/h1-4,7-8H Y
    Key: JRNVQLOKVMWBFR-UHFFFAOYSA-N Y
  • InChI=1/C6H6S2/c7-5-3-1-2-4-6(5)8/h1-4,7-8H
    Key: JRNVQLOKVMWBFR-UHFFFAOYAM
  • C1=CC=C(C(=C1)S)S
  • Sc1ccccc1S
Properties
C6H6S2
Molar mass 142.24 g/mol
Appearance colourless liquid
Density 1.236 g/mL
Melting point 22 to 24 °C (72 to 75 °F; 295 to 297 K)
Boiling point 119 to 120 °C (246 to 248 °F; 392 to 393 K) at 17 mmHg
Soluble in basic water
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
stench
Flash point 104.0 °C; 219.2 °F; 377.1 K
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references
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