Ammonium fluorosilicate

Ammonium fluorosilicate (also known as ammonium hexafluorosilicate, ammonium fluosilicate or ammonium silicofluoride) has the formula (NH4)2SiF6. It is a toxic chemical, like all salts of fluorosilicic acid. It is made of white crystals, which have at least three polymorphs and appears in nature as rare minerals cryptohalite or bararite.

Ammonium fluorosilicate
Names
IUPAC name
Ammonium hexafluorosilicate
Other names
Ammonium fluorosilicate

Ammonium fluosilicate

Ammonium silicofluoride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.037.229
EC Number
  • 240-968-3
RTECS number
  • VV7800000
UNII
UN number 2854
  • InChI=1S/F6Si.2H3N/c1-7(2,3,4,5)6;;/h;2*1H3/q-2;;/p+2 Y
    Key: ITHIMUMYFVCXSL-UHFFFAOYSA-P Y
  • InChI=1/F6Si.2H3N/c1-7(2,3,4,5)6;;/h;2*1H3/q-2;;/p+2
    Key: ITHIMUMYFVCXSL-SKRXCDHZAK
  • F[Si-2](F)(F)(F)(F)F.[NH4+].[NH4+]
  • [NH4+].[NH4+].F[Si--](F)(F)(F)(F)F
Properties
(NH4)2[SiF6]
Appearance White crystals
Density 2.0 g cm−3
Melting point 100 °C (212 °F; 373 K) (decomposes)
Solubility dissolves in water and alcohol
Related compounds
Other cations
Hexafluorosilicic acid

Sodium fluorosilicate

Hazards
GHS labelling:
Danger
H301, H311, H315, H319, H331, H335, H372
P260, P261, P264, P270, P271, P280, P301+P310, P302+P352, P304+P340, P305+P351+P338, P312, P314, P321, P330, P332+P313, P337+P313, P362, P403+P233, P405, P501
NFPA 704 (fire diamond)
Safety data sheet (SDS) ChemicalBook MSDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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