Ammonium azide
Ammonium azide is the chemical compound with the formula [NH4]N3, being the salt of ammonia and hydrazoic acid. Like other inorganic azides, this colourless crystalline salt is a powerful explosive, although it has a remarkably low sensitivity. [NH4]N3 is physiologically active and inhalation of small amounts causes headaches and palpitations. It was first obtained by Theodor Curtius in 1890, along with other azides.
Names | |
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IUPAC name
Ammonium azide | |
Other names
Ammonium trinitride | |
Identifiers | |
3D model (JSmol) |
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ChemSpider | |
ECHA InfoCard | 100.032.093 |
EC Number |
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PubChem CID |
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CompTox Dashboard (EPA) |
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Properties | |
[NH4]N3 | |
Molar mass | 60.059 g/mol |
Appearance | White crystalline solid |
Odor | Odorless |
Density | 1.3459 g/cm3 |
Melting point | 160 °C (320 °F; 433 K) |
Boiling point | 400 °C (752 °F; 673 K) (decomposes) |
Structure | |
Orthorhombic | |
Pman | |
a = 8.930, b = 8.642, c = 3.800 | |
Formula units (Z) |
4 |
Hazards | |
Occupational safety and health (OHS/OSH): | |
Main hazards |
Very toxic, explosive |
Related compounds | |
Other anions |
Ammonium nitrate Ammonium cyanide Ammonium carbamate |
Other cations |
Lithium azide Sodium azide Potassium azide Rubidium azide Caesium azide Silver azide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references |
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