Adamsite

Adamsite or DM is an organic compound; technically, an arsenical diphenylaminechlorarsine, that can be used as a riot control agent. DM belongs to the group of chemical warfare agents known as vomiting agents or sneeze gases. First synthesized in Germany by Heinrich Otto Wieland in 1915, it was independently developed by the US chemist Roger Adams (for whom it is named) at the University of Illinois in 1918.

Adamsite
Names
Preferred IUPAC name
10-Chloro-5,10-dihydrophenazarsinine
Other names
10-Chloro-5H-phenarsazinine
Diphenylaminechlorarsine
Identifiers
3D model (JSmol)
Abbreviations DM
ChemSpider
ECHA InfoCard 100.008.577
EC Number
  • 209-433-1
MeSH Phenarsazine+chloride
UNII
  • InChI=1S/C12H9AsClN/c14-13-9-5-1-3-7-11(9)15-12-8-4-2-6-10(12)13/h1-8,15H Y
    Key: PBNSPNYJYOYWTA-UHFFFAOYSA-N Y
  • InChI=1/C12H9AsClN/c14-13-9-5-1-3-7-11(9)15-12-8-4-2-6-10(12)13/h1-8,15H
    Key: PBNSPNYJYOYWTA-UHFFFAOYAA
  • Cl[As]2c1ccccc1Nc3c2cccc3
  • Cl[As]1C2=C(NC3=C1C=CC=C3)C=CC=C2
Properties
C12H9AsClN
Molar mass 277.58 g·mol−1
Appearance Yellow-green crystals
Melting point 195 °C (383 °F; 468 K)
Boiling point 410 °C (770 °F; 683 K)
0.064 g dm−3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references
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