Acanthite

Acanthite is a form of silver sulfide with the chemical formula Ag2S. It crystallizes in the monoclinic system and is the stable form of silver sulfide below 173 °C (343 °F). Argentite is the stable form above that temperature. As argentite cools below that temperature its cubic form is distorted to the monoclinic form of acanthite. Below 173 °C acanthite forms directly. Acanthite is the only stable form in normal air temperature.

Acanthite
Crystallized acanthite (4.0 × 2.5 × 1.5 cm) from Imiter mine, Jbel Saghro mountain range, Morocco
General
CategorySulfide mineral
Formula
(repeating unit)
Ag2S
IMA symbolAca
Strunz classification2.BA.30a
Crystal systemMonoclinic
Crystal classPrismatic (2/m)
(same H-M symbol)
Space groupP21/n
Unit cella = 4.229 Å, b = 6.931 Å
c = 7.862 Å; β = 99.61°; Z = 4
Identification
ColorIron-black
Crystal habitPrimary crystals rare, prismatic to long prismatic, elongated along [001], may be tubular; massive. Commonly paramorphic after the cubic high-temperature phase ("argentite"), of original cubic or octahedral habit
TwinningPolysynthetic on {111}, may be very complex due to inversion; contact on {101}
CleavageIndistinct
FractureUneven
TenacitySectile
Mohs scale hardness2.0–2.5
LusterMetallic
StreakBlack
DiaphaneityOpaque
Specific gravity7.20–7.22
References
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