Two-dimensional polymer

A two-dimensional polymer (2DP) is a sheet-like monomolecular macromolecule consisting of laterally connected repeat units with end groups along all edges. This recent definition of 2DP is based on Hermann Staudinger's polymer concept from the 1920s. According to this, covalent long chain molecules ("Makromoleküle") do exist and are composed of a sequence of linearly connected repeat units and end groups at both termini.

Moving from one dimension to two offers access to surface morphologies such as increased surface area, porous membranes, and possibly in-plane pi orbital-conjugation for enhanced electronic properties. They are distinct from other families of polymers because 2D polymers can be isolated as multilayer crystals or as individual sheets.

The term 2D polymer has also been used more broadly to include linear polymerizations performed at interfaces, layered non-covalent assemblies, or to irregularly cross-linked polymers confined to surfaces or layered films. 2D polymers can be organized based on these methods of linking (monomer interaction): covalently linked monomers, coordination polymers and supramolecular polymers. 2D polymers containing pores are also known as porous polymers.

Topologically, 2DPs may thus be understood as structures made up from regularly tessellated regular polygons (the repeat units). Figure 1 displays the key features of a linear and a 2DP according to this definition. For usage of the term "2D polymer" in a wider sense, see "History".