Post-processing simply means you just use your Python programming skills to manipulate the output; at this point the problem has nothing to do with z3. For the specific example you're referring to, you can modify it to:
from z3 import *
v = [Real('v_%s' % (i+1)) for i in range(10)]
s = Solver()
for i in range(10):
s.add(v[i] == i)
if s.check() == sat:
m = s.model()
print (sorted ([(d, m[d]) for d in m], key = lambda x: int(str(x[0])[2:])))
which prints:
[(v_1, 0), (v_2, 1), (v_3, 2), (v_4, 3), (v_5, 4), (v_6, 5), (v_7, 6), (v_8, 7), (v_9, 8), (v_10, 9)]
sorting the keys numerically. But again, this isn't really a z3 question: You can take this output and just perform regular Python programming on it as you wish.