If you're given a pure state and promised that it's separable, you don't need the Schmidt decomposition to compute the parts. Just lay the amplitudes out in a grid, read off the proportions between the columns for one part and read off the proportions between the rows for the other.
That is to say, the statement that a 2-qubit system φ is separable so φ = αβ guarantees that φ₀₀/φ₀₁ = φ₁₀/φ₁₁ = β₀/β₁ and that φ₀₀/φ₁₀ = φ₀₁/φ₁₁ = α₀/α₁. And knowing α₀/α₁ is enough to solve for α, except for the global phase factor. (Note: work with proportions α₀:α₁ instead of ratios α₀/α₁ if α₁ might be zero.)
This generalizes to systems with more qubits. A given subset of qubits is separable if and only if grouping by all the other qubits gives you a bunch of parts with agreeing proportions between their pieces. And the proportions between the pieces constrain everything except the global phase factor.
Using the Schmidt decomposition as a shortcut
The Schmidt decomposition does make this easier. It does all the hard 'reconstructing the proportions' work. If a pure system is separable then its SVD decomposition should only have one non-zero singular value, and that singular value should equal 1. So you have something like:
|1 0 0 ...|
U |0 0 0 ...| V
|0 0 0 ...|
|... . ...|
But that's just multiplying the first column of U by the first row of V! So we have a system with n*m entries being created from a system with n entries and a system with m entries... Yup, the first column and the first row contain the amplitudes of α and β.
Example
My circuit simulator Quirk has built-in inline amplitude displays that perform this kind of separation (without doing an SVD). You can see the code that does it on github, though it's all GPU based so not particularly clear.
(It was by far the most complicated display to write, since it has to do the grouping then compare all the groups. But some groups might have no amplitude so they have to be ignored, and there may be noise in the system from float errors so you should focus on the big groups and... blergh.)
Also you can play with it in the simulator itself. Here's an example circuit using those displays:

You might also find this blog post intuitively useful.